The different expression for the solubility products

(i) Electrolyte of type AB (1 : 1 type salt) e.g., AgCl, BaSO₄

 (ii) Electrolytes of type AB₂ (1:2 type salt) e.g., PbCl2, CaF₂

(iii) Electrolyte of type A₂B (2 : 1 type salt) e.g.,Ag₂CrO₄, H₂S

(iv) Electrolyte of type A₂B₃ (2 : 3 type salt)

 E.g., As2S3, Sb₂S₃

(v) Electrolyte of type AB₃ (1 : 3 type salt)

 e.g.,AlCl₃, Fe(OH)₃

The criteria of precipitation of an electrolyte: When the Ionic product of an electrolyte is greater than the solubility product of it, precipitation occurs. 

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