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Electrons and Holes

  • For T> 0 K, there would be some electrons in otherwise empty conduction band, and some empty states in otherwise filled valence band.
  • The empty states in valence band are referred as holes.
  • If conduction band electron and the valence band hole are created by the thermal excitation of the valence band electron to conduction band, then they are called as electron-hole pair (EHP).
  • After excitation to conduction band, an electron is surrounded by the large number of empty states, for example the equilibrium number of EHPs at the temperature 300 K in Si is ≈ 1010/cm3, whereas Si atom density is  ≈ 1022/cm3.
  • Therefore, electrons in the conduction band are free to move about using many available empty states.
  • The corresponding problem of charge transport in the valence band is a bit more complex.
  • Current transport in valence band can be accounted for by keeping track of holes themselves.
  • In the filled band, all the available energy states are pre occupied.
  • For every electron moving with the given velocity, there is equal and opposite electron motion somewhere else in band.
  • Under the applied electric field, net current is zero, as for every electron j moving with the velocity Vj, there is corresponding electron j' moving with the velocity -Vj .
  • In the unit volume, current density J can be given as

2454_electrons and holes.png  (filled band)                                    (2.2)

here N is number of  electrons/cmin band, and q is electronic charge.

  • Now, if jth electron is removed and the hole is created in valence band, then the net current density can be given as

 

2118_electrons and holes1.png

 

  • Therefore, the current contribution of empty state (hole), obtained by removing jth electron, is equivalent to that of the positively charged particle with the velocity Vj.
  • Note that this transport is accounted for by the motion of the uncompensated electron J' possesing a charge of q and moving with the velocity  Vj.
  • The current contribution (- q)(-  Vj) is equivalent to that of the positively charged particle with the velocity +  Vj .
  • For simplicity, the empty states in valence band are called as holes, and they are assigned positive charge and the positive mass.
  • The electron energy increases as one moves up the conduction band, and electrons gravitate downward towards bottom of conduction band.
  • Conversely hole energy increases as one moves down the valence band (as the holes have positive charges), and holes gravitate upwards towards the top of valence band.

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