Electrons and Holes
- For T> 0 K, there would be some electrons in otherwise empty conduction band, and some empty states in otherwise filled valence band.
- The empty states in valence band are referred as holes.
- If conduction band electron and the valence band hole are created by the thermal excitation of the valence band electron to conduction band, then they are called as electron-hole pair (EHP).
- After excitation to conduction band, an electron is surrounded by the large number of empty states, for example the equilibrium number of EHPs at the temperature 300 K in Si is ≈ 1010/cm3, whereas Si atom density is ≈ 1022/cm3.
- Therefore, electrons in the conduction band are free to move about using many available empty states.
- The corresponding problem of charge transport in the valence band is a bit more complex.
- Current transport in valence band can be accounted for by keeping track of holes themselves.
- In the filled band, all the available energy states are pre occupied.
- For every electron moving with the given velocity, there is equal and opposite electron motion somewhere else in band.
- Under the applied electric field, net current is zero, as for every electron j moving with the velocity Vj, there is corresponding electron j' moving with the velocity -Vj .
- In the unit volume, current density J can be given as
(filled band) (2.2)
here N is number of electrons/cm3 in band, and q is electronic charge.
- Now, if jth electron is removed and the hole is created in valence band, then the net current density can be given as
- Therefore, the current contribution of empty state (hole), obtained by removing jth electron, is equivalent to that of the positively charged particle with the velocity Vj.
- Note that this transport is accounted for by the motion of the uncompensated electron J' possesing a charge of q and moving with the velocity Vj.
- The current contribution (- q)(- Vj) is equivalent to that of the positively charged particle with the velocity + Vj .
- For simplicity, the empty states in valence band are called as holes, and they are assigned positive charge and the positive mass.
- The electron energy increases as one moves up the conduction band, and electrons gravitate downward towards bottom of conduction band.
- Conversely hole energy increases as one moves down the valence band (as the holes have positive charges), and holes gravitate upwards towards the top of valence band.
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