The Electronic configurations of the elements
On the basis of electronic configuration principles the electronic configuration of the various elements are given in the table given as follows :
The above method or technique of writing the electronic configurations is much cumbersome. Hence, generally the electronic configuration of an atom of any of the element is simply represented by the notation.
Some of the Unexpected Electronic Configuration
Some of the exceptions are significant though, because they occur with the common elements, particularly chromium and copper.
The Cu has 29 electrons. Its excepted electronic configuration can be given as but in actuality the configuration is given as as this configuration is much more stable. Similarly Cr has configuration of instead of .
The factors responsible for the extra stability of the half-filled and the completely filled subshells,
(i) Symmetrical distribution: It is a well known fact that the symmetry leads to the stability. Hence the electronic configuration in which all orbitals of the same subshell are either completely filled or are exactly half filled are much more stable because of the symmetrical distribution of electrons.
(ii) Exchange energy: The electrons with the parallel spins present in the degenerate orbitals have a tendency to exchange their position. The energy released during this type of exchange is known as exchange energy. The number of exchanges which can take place is maximum when the degenerate orbtials (orbitals of the same subshell having equal amount of energy) are exactly half-filled or completely filled. As a result which the exchange energy is maximum and so is the stability.
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