Degree of unsaturation, Alkynes Hydrobarbon Assignment Help

Assignment Help: >> Alkynes >> Degree of unsaturation, Alkynes Hydrobarbon

Degree of unsaturation : The number of degree of unsaturation in a hydrocarbon is given by (2n1 + 2 -n2)/ 2,

Where n1 is the number of carbon atoms; n2 is the number of hydrogen atoms.

         For example in C6H12, the degree of unsaturation is = (2 * 6 + 2 -12)/2 = 1

         Tests of unsaturation

         (a) Baeyer's reagent : It is 1% KMnO4 solution containing sodium carbonate. It has pink colour. An aqueous solution of the element, a few drops of Baeyer's reagent are included, the pink colour of the solution disappears. The decolourisation of pink colour indicates the presence of unsaturation in the compound.

  • Alkene without any hydrogen molecules on the carbon forming the double bond   1253_unsaturation.png don't show this test.

         (b) Bromine- carbon tetrachloride test : The compound is dissolved in carbon tetrachloride or chloroform and then a few drops of 5% bromine solution in carbon tetrachloride are included to it, the colour of bromine disappears.  It shows the existence of unsaturation.

  • This test also not pass in the type of alkene of the 2456_unsaturation1.png .

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