Degree of unsaturation : The number of degree of unsaturation in a hydrocarbon is given by (2n1 + 2 -n2)/ 2,
Where n1 is the number of carbon atoms; n2 is the number of hydrogen atoms.
For example in C6H12, the degree of unsaturation is = (2 * 6 + 2 -12)/2 = 1
Tests of unsaturation
(a) Baeyer's reagent : It is 1% KMnO4 solution containing sodium carbonate. It has pink colour. An aqueous solution of the element, a few drops of Baeyer's reagent are included, the pink colour of the solution disappears. The decolourisation of pink colour indicates the presence of unsaturation in the compound.
- Alkene without any hydrogen molecules on the carbon forming the double bond don't show this test.
(b) Bromine- carbon tetrachloride test : The compound is dissolved in carbon tetrachloride or chloroform and then a few drops of 5% bromine solution in carbon tetrachloride are included to it, the colour of bromine disappears. It shows the existence of unsaturation.
- This test also not pass in the type of alkene of the .
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