Sodium peroxide (Na2O2)
Preparation : It is manufactured by heating sodium metal on aluminium trays in air (free from CO2)
Properties : (a) When pure it is colourless. The faded yellow colour of the commercial product is because of presence of small amount of superoxide (Na2O)
(b) On coming with moist air it become white because of the formation of NaOH and Na2CO3.
(c) It is powerful oxidising agent. It oxidises the Cr(III) hydroxide to sodium chromate, Mn(II) to obtain sodium manganate and sulphides to the sulphates of it.
Uses : As a bleaching agent and it is used for the purification of air in confined spaces such as submarines because it can combine with CO2 to give Na2CO3 and oxygen, .
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