Compounds of Gold, d-block elements Assignment Help

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The compounds of gold

(1) Auric chloride, AuCl3 : It can prepared by passing dry Cl2 over finely divided gold powder at the temperature of 573 K

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This is a red colored crystalline solid which is soluble in water and decomposes on heating to give gold (I) chloride and Cl2

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It dissolves in concentratedHCl forming chloroauric acid

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Chloroauric acid is used in the photography for toning silver prints and as an antidote for the snake poisoning.

(2) Aurous sulphide, Au2S : It is prepared when H2S is passed through an acidified solution of potassium aurocyanide, K[Au(CN)2]

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It is a dark brown solid, not attached by the dilute mineral acids and therefore is probably the most stable gold compound.

 

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