Chemical properties of Trihydric Alcohols, Hydroxy Compounds Assignment Help

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Chemical properties of Trihydric Alcohols

         (i) Reaction with sodium

         2227_chemical properties of trihydric alcohol.png

 

         (ii) Reaction with HCl or HBr

            679_chemical properties of trihydric alcohol1.png

         (iii) Reaction with HI

 

         1703_chemical properties of trihydric alcohol2.png

         (iv) Reaction with oxalic acid

         (a) At 110°C Glycerol is formed

223_chemical properties of trihydric alcohol3.png

         (b) At 260°C, allyl alcohol is formed

368_chemical properties of trihydric alcohol4.png

 

(v) Dehydration

             488_chemical properties of trihydric alcohol5.png 

         (vi) Reaction with nitric acid

                        1990_chemical properties of trihydric alcohol6.png

 

Dynamite is prepared from T.N.G.

         Dynamite : A mixture of T.N.G. and glyceryl dinitrate absorbed in kieselguhr is known as dynamite. It was found by Alfred. Nobel in 1867. It frees large volume of gases and obtained 10,900 times the mass of nitroglycerine.

         927_chemical properties of trihydric alcohol7.png

         Blasting gelatin : A mixture of glyceryl trinitrate and cellulose nitrate (gun cotton).

         Cordite : It is found by mixing glyceryl trinitrate with gun cotton and vaseline it is smokeless explosive.

 

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