Chemical properties of Halo-arenes

         Inert nature of chlorobenzene : Aryl halides are unreactive as compared to alkyl halides as the halogen atom in these compounds is firmly attached and cannot be replaced by nucleophiles. Such as OH^-, NH₂^-, CN^- etc.

         Thus delocalization of electrons by resonance in aryl halides, calls extra double bond and stability character between

C-X bond. This makes the bond stronger and shorter than perfect single bond. However under various situations the following nucleophilic substitution reactions are observed,

         (i) Nucleophilic displacement :

         (ii) Electrophilic aromatic substitution 

         (iii) Wurtz - fittig reaction :

         (iv) Formation of grignard reagent :

         (v) Ullmann reaction

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