Chemical properties of alkyl cyanide
(a) Hydrolysis
(b) Reduction : When reduced with hydrogen in presence of Pt or Ni, or LiAlH4 (Lithium aluminium hydride) or sodium and alcohol, alkyl cyanides yield primary amines.
However, when a solution of alkyl cyanides in ether is reduced with stannous chloride and hydrochloric acid and then steam distilled, an aldehyde is formed (Stephen's reaction).
(c) Reaction with Grignard reagent : With grignard's reagent, an alkyl cyanide forms a ketone which further reacts to form a tertiary alcohol.
(d) Alcohololysis :
Uses : Alkyl cyanides are important intermediates in the organic synthesis of a large number of compounds like acids, amides, esters, amines etc.
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