Chemical properties of Acyl Halides Assignment Help

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Chemical properties

2482_chemical properties of acyl halide.png

      (i) Hydrolysis : 529_chemical properties of acyl halide1.png

       992_chemical properties of acyl halide2.png

      (ii)  Reaction with alcohols (alcoholysis)

      325_chemical properties of acyl halide3.png

      This reaction is known as Schotten Baumann reaction.

      (iii) Reaction with salts of carboxylic acid

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         (iv) Reaction with benzene (acylation) : This reaction is called friedel craft reaction.

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         (v) Reaction with ammonia or amines :  

         2277_chemical properties of acyl halide6.png

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         (vi) Reduction :  

         566_chemical properties of acyl halide8.png

         This reaction is known as Rosenmund reaction.

         (vii) Reaction with organocadmium compounds (formation of ketones)

         31_chemical properties of acyl halide9.png

         (viii) Reaction with diazomethane

         2390_chemical properties of acyl halide10.png

         (ix) Reaction with Grignard reagent

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         (x) Reaction with Salicylic acid

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         (xi) Reaction with sodium peroxide (Peroxide formation)

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         (xii) Reaction with hydroxylamine and hydrazine

         625_chemical properties of acyl halide15.png

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