Chemical properties
(i) Hydrolysis
(ii) Amphoteric nature (Salt formation)
It shows feebly acidic as well as basic nature.
(iii) Reduction
(iv) Dehydration
(v) Reaction with nitrous acid
(vi) Hofmann bromamide reaction or Hofmann degradation : This is an important reaction for reducing a carbon atom from a compound, i.e.,-CO NH2 is changed to -NH2 group.
- In this reaction a value of intermediates have been isolated; N-bromamides, RCONHBr; salts of these bromamides [RCONBr-]K+ ; Isocyanates, RNCO.
- Nitrene rearranges to form isocyanate.
(vii) Reaction with grignard reagent
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