Chain transfer agents : In Vinylic polymerisation various other molecules react with main growing chain to interrupt the further growth of the original chain. This takes lowering of average atomic mass of the polymer such reagents are called chain transfer agents. The common example CCl4, CBr4 etc.
For example in the presence of CCl4 styrene polymerizes to form a polymer of lower average molecular mass which also contains some chlorine.
Chain transfer agents calculated chain reaction and inhibit further polymerisation and are also called inhibitors.
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