Boron Halides

          Boron reacts with halogens on strong heating to form boron halides .

         BF₃ and BCl₃ are gases, BBr₃ is a volatile liquid while BI₃ is a solid.

         In these halides, the central boron atom has three shared pairs of electrons with the halogen atoms. Therefore, these have two electrons less than the octet and are electron deficient compounds. They acts as Lewis acids.

   The relative acidic strength of boron trihalides decreases as :

BI₃ > BBr₃ > BCl₃ > BF₃.

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