Borax (Na2B4O7.10H2O)
It occurs naturally as tincal (Suhaga) which contains about 50% borax in certain land, lakes. It is also obtained from the mineral colemanite by boiling it with a solution of Na2CO3.
Properties : (a) Its aqueous solution is alkaline due to hydrolysis,
Na2B4O7 + 7H2O → 2NaOH+4H3BO3.
(b) On heating borax loses its water of crystallization and swells up to form a fluffy mass. On further heating, it melts to give a clear liquid which solidifies to a transparent glassy bead consisting of sodium metaborate (NaBO2) and boric anhydride (B2O3),
Borax bead is used for the detection of coloured basic radicals under the name borax bead test.
Borax bead test : Borax bead is a mixture of NaBO2 and B2O3.B2O3 on heating combines readily with a number of coloured transition metal oxides such as Ni, Co, Mn, Cr, Cu, etc. to form corresponding metaborates which possess characteristic colours,
Colours of some significant metaborates are: Cupric metaborate, Cu(BO2)2 is dark blue, chromium metaborate, Cr(BO2)2 is green, nickel metaborate, Ni(BO2)2 is brown and manganese metaborate, Mn(BO2)2 is pink violet.
When heated with C2H5OH and conc.H2SO4, it gives volatile vapours of triethyl borate which burns with a green edged flame.
This type of reaction is used as a test for borate radical in the qualitative analysis.
Uses :
(a) In the making optical and hard glasses.
(b) In laboratory for the borax bead test.
(c) In softening of the water.
(d) In preparation of the medicinal soaps because of its antiseptic character.
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