Covalent Bonding
- The property is exhibited by the diamond lattice semiconductors.
- Each atom surrounded by the 4 nearest neighbors, each having four electrons in outermost orbit.
- Each atom shares its valence electrons with the 4 nearest neighbors.
- The bonding forces arise from the quantum mechanical interaction among the shared electrons.
- Both the electrons belong to each bond, can't be distinguished, and have opposite spins.
- No free electrons are available at 0 K, but, by the thermal or optical excitation, electrons can be excited out of the covalent bond and can take part in current conduction → significant feature of semiconductors.
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