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Benzyne

         (1) 1, 2-Didehydrobenzene, C6H6 and its derivatives are called benzyne or arynes and the simplest member is benzyne.

         (2) It is neutral reaction substance created from benzene ring by removing two substituents, of ortho positions, one in the form of electrophile and other in the form of nucleophile leaving behind two electrons to be distributed between two orbitals.

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         (3) Benzyne substances is aromatic in behavior.

         (4) When halobenzene is heated with sodamide creation of benzyne takes place.

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         (5) (i) It acts as dienophile and provides Diels-Alder reaction with diene.

         (ii) It acts with strong nucleophile like 835_benzyne2.png

817_benzyne3.png 

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