Alkyl Cyanide, Nitrogen containing Compounds Assignment Help

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Alkyl Cyanides

         (i) Methods of preparation

         (a) From alkyl halides : The disadvantage of this method is that a mixture of nitrile and isonitrile is formed.

         1379_alkyl cyanide.png

         (b) From acid amides2367_alkyl cyanide1.png  

             1200_alkyl cyanide2.png

         Industrially, alkyl cyanides are formed by passing a mixture of carboxylic acid and ammonia over alumina at 500°C.

         1483_alkyl cyanide3.png

         (c) From Grignard reagent

         1173_alkyl cyanide4.png

         (d) From primary amines : Primary amines are dehydrogenated at high temperature to form alkyl cyanides. This is also a commercial method.

            776_alkyl cyanide5.png

         (e) From oximes :

            423_alkyl cyanide6.png

 

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