Advantages of Bohr's theory
(i) Bohr's theory satisfactorily explains the spectra of species having one electron, viz. hydrogen atom, He+, Li2+etc.
(ii) Calculation of radius of Bohr's orbit : According to Bohr, radius of nth orbit in which electron moves is
Where, n = Orbit number, m = Mass number (9.1 * 10-31 Kg), e = Charge on the electron (1.6 * 10-19) z = Atomic number of element, k = Coulombic constant 9 * 109Nm2c-2
After we put the values of m,e,k,h, we obtain.
(iii) Calculation of the velocity of an electron
(iv) Calculation of the energy of electron in the Bohr's orbit
Total energy of electron = K.E. + P.E. of electron
Substituting of r, gives us Where, n=1, 2, 3..........
Putting the value of m, e, k, h,∏ we obtain
When the electron jumps from the outer orbit (which is higher energy) n2 to the inner orbit (which is lower energy) n1 then the energy is emitted in the form of radiation which is given by
As we know that and
This can be represented as
Where, ; R is known as Rydberg constant. Hear the value to be used is 109678 cm-1
The negative sign in above equations signifies that the electron and the nucleus form a bound system, which means that the electron is attracted towards the nucleus. Hence, if electron is to be taken away from nucleus, energy has to be supplied. The energy of the electron in n = 1 orbit is known the ground state energy; that in the n = 2 orbit is called the first excited state
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