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Advantages of Bohr's theory

(i) Bohr's theory satisfactorily explains the spectra of species having one electron, viz. hydrogen atom, He+, Li2+etc.

(ii) Calculation of radius of Bohr's orbit : According to Bohr, radius of  nth orbit in which electron moves is

166_Bohr model2 (1).png

      Where, n = Orbit number, m = Mass number (9.1 * 10-31 Kg), e = Charge on the electron (1.6 * 10-19) z = Atomic number of element, k = Coulombic constant 9 * 109Nm2c-2

After we put the values of m,e,k,h, we obtain.

1328_Bohr model2 (2).png 

 (iii) Calculation of the velocity of an electron

1572_Bohr model4 (2).png

(iv) Calculation of the energy of electron in the Bohr's orbit

Total energy of electron = K.E. + P.E. of electron 933_Bohr model4 (1).png

Substituting of r, gives us  938_Bohr model6 (2).png  Where, n=1, 2, 3..........

Putting the value of m, e, k, h,∏ we obtain

298_Bohr model6 (1).png

      2167_Bohr model7.png 

When the electron jumps from the outer orbit (which is higher energy) nto the inner orbit (which is lower energy) n1 then the energy is emitted in the form of radiation which is given by

632_Bohr model8 (1).png

 

As we know that  20_Bohr model8 (2).png and  2493_Bohr model10 (1).png  

400_Bohr model10 (2).png

This can be represented as 1986_Bohr model12 (1).png

Where,  2318_Bohr model12 (2).png ; R is known as Rydberg constant. Hear the value to be used is 109678 cm-1 

            The negative sign in above equations signifies that the electron and the nucleus form a bound system, which means that the electron is attracted towards the nucleus. Hence, if electron is to be taken away from nucleus, energy has to be supplied. The energy of the electron in n = 1 orbit is known the ground state energy; that in the n = 2 orbit is called the first excited state

 

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