Acidic character of Nitroalkanes :The α-hydrogen atom of primary and secondary nitroalkanes are weakly acidic and thus can be abstracted by strong alkalies like aq. NaOH. Therefore, 1° and 2° nitroalkanes dissolve in aq. NaOH to form salts. For examples.
Thus 1° and 2° nitroalkanes are acidic mainly due to following two reasons,
(a) Strong electron withdrawing method of the - NO2 group.
(b) Resonance stabilisation of the carbanion (I) formed after the removal of proton.
The aci-form of nitroalkanes is relatively more acidic because it produces relatively more conjugate base.
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