Acetylene tetrachloride (Westron), CHCl2·CHCl2 : Acetylene tetrachloride is also called as sym. tetrachloroethane. It is created by the action of chlorine on acetylene in presence of a catalyst such as aluminium chloride, iron, ferric chloride, quartz or kieselguhr.
In absence of catalyst, the reaction between chlorine and acetylene is highly explosive producing HCl and carbon. The reaction is less violent in occurrence of a catalyst.
It is a heavy, non-inflammable liquid. It boils at 146°C. It is highly toxic in nature. Its smell is similar to chloroform. It is not soluble with water but soluble in organic solvents.
On further chlorination, it forms hexa and pentachloroethane. On heating with Calcium hydroxide, it is converted to useful product westrosol (CCl2=CHCl).
Both westron and westrosol are used as solvents for oils, fats, waxes, resins, varnishes and paints, etc.
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